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Time averaged total force on a dipolar sphere in an electromagnetic eld Opt Lett 25(15):1065 1067 Chen JP, Labarthet FL, Natansohn A, Rochon P 1999 Highly stable optically induced birefringence and holographic surface gratings on a new azocarbazole based polyimide Macromolecules 32(25):8572 8579 Chun CM, Kim MJ, Vak D, Kim DY 2003 A novel azobenzene based amorphous molecular material with a spiro linked bi uorene J Materials Chem 13(12):2904 2909 Ciuchi F, Mazzulla A, Cipparrone G 2002 Permanent polarization gratings in elastomer azo dye systems: comparison of layered and mixed samples J Opt Soc Am B 19(11):2531 2537 Ciuchi F, Mazzulla A, Carbone G, Cipparrone G 2003 Complex structures of surface relief induced by holographic recording in azo dye doped elastomer thin lms Macro molecules 36(15):5689 5693 Delaire JA, Nakatani K 2000 Linear and nonlinear optical properties of photochromic molecules and materials Chem Rev 100(5):1817 1846 Dumarcher V, et al.

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2000 Polymer thin lm distributed feedback tunable lasers J Opt A: Pure Appl Opt 2(4):279 283 Egami C, et al 2000 Two stage optical data storage in azo polymers Jpn J Appl Phys 1 39(3B):1558 1561 Forrest JA, Dalnoki Veress K 2001 The glass transition in thin polymer lms Adv Colloid Interface Sci 94(1 3):167 196 Fukuda T, et al 2000a Photofabrication of surface relief grating on lms of azobenzene polymer with different dye functionalization Macromolecules 33(11):4220 4225 Fukuda T, Sumaru K, Yamanaka T, Matsuda H 2000b Photo induced formation of the surface relief grating on azobenzene polymers: analysis based on the uid mechanics Mol Cryst Liq Cryst 345:587 592 Fukuda T, et al 2001 Observation of optical near eld as photo induced surface relief formation Jpn J Appl Phys 2 40(8B):L900 L902 Geue T, et al 2000 X ray investigations of the molecular mobility within polymer surface gratings.

pH = 2 (redox potentials of the system thionine/semithionine).

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395 The participation of 5* molecules in homogeneous redox processes is mainly controlled by their short lifetimes. The lifetime of 5* is shortened by a bimolecular redox reaction (5.10.3) or (5.10.4) as follows: (kT is a rate constant of the quenching reaction and c is a concentration of the reactant D or A). Equation (5.10.7) can be rearranged to a more practical form:

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Geue T, et al 2002a Formation of a buried density grating on thermal erasure of azobenzene polymer surface gratings Coll Surf A 198 200:31 36 Geue T, Henneberg O, Pietsch U 2002b X ray re ectivity from sinusoidal surface relief gratings Cryst Res Technol 37(7):770 776 Geue TM, et al 2002c Formation mechanism and dynamics in polymer surface gratings Phys Rev E 65(5):052801 Geue TM, et al 2003 X ray investigations of formation ef ciency of buried azobenzene polymer density gratings J Appl Phys 93(6):3161 3166 Gordon JP 1973 Radiation Forces and Momenta in Dielectric Media Phys Rev A 8(1):14 21 Hasegawa M, Ikawa T, Tsuchimori M, Watanabe O, Kawata Y 2001 Topographical nanostructure patterning on the surface of a thin lm of polyurethane containing azobenzene moiety using the optical near eld around polystyrene spheres Macro molecules 34(21):7471 7476 Hasegawa M, Keum C D, Watanabe O 2002.

TQ/ T = 1 /v.sv^ v^ J-0. o)

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where Ksv = rokr is the so-called Stern-Volmer constant. Figure 5.58 presents a general scheme of photogalvanic cells based on reductive (a) or oxidative (b) quenching of 5*. These cells are regenerative if D and A are two forms of the same redox couple (D + = A and D =A~), otherwise the products D + and A~ accumulate in the electrolyte and the cell is photoelectrosynthetic. Some properties of three typical photoredox-active dyes are summarized in Table 5.6. The most important photogalvanic system is based on the photoredox reaction of thionine with Fe 2+ . It was first studied by E. Rabinowitch in 1940 and recently optimized by J. W. Albery et al. The structural formula of thionine, Thi+ and its reduction products (Sem+, Leu2+) are as follows:

Enhanced photofabrication of a surface nanostructure on azobenzene functionalized polymer lms with evaporated gold Nanoislands Adv Mater 14(23):1738 1741 He J A, et al 2000a Photochemical behavior and formation of surface relief grating on self assembled polyion/dye composite lm J Phys Chem B 104(45):10513 10521 He J A, et al 2000b Surface relief gratings from electrostatically layered azo dye lms Appl Phys Lett 76(22):3233 3235 Helgert M, Fleck B, Wenke L, Hvilsted S, Ramanujam PS 2000 An improved method for separating the kinetics of anisotropic and topographic gratings in side chain azobenzene polyesters Appl Phys B Lasers O 70(6):803 807 Helgert M, Wenke L, Hvilsted S, Ramanujam PS 2001 Surface relief measurements in side chain azobenzene polyesters with different substituents Appl Phys B: Lasers Opt 72(4):429 433 Henneberg O, et al 2001a Atomic force microscopy inspection of the early state of formation of polymer surface relief gratings.

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