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392 in detail by H. Gerischer. The photogalvanic effect was first interpreted in 1940 by E. Rabinowitch, and more recently studied by W. J. Albery, M. D. Archer and others. Besides the classification of photoelectrochemical effects (cells) according to the nature of the light-absorbing system, we can also distinguish them according to the effective Gibbs free energy change in the electrolyte, AG: 1. AG = 0: Regenerative photoelectrochemical cell. The reactants consumed during the photoredox process (either in homogeneous phase or at the semiconductor photoelectrode) are immediately regenerated by subsequent electrode reactions. The net output of the cell is an electrical current flowing through the cell and an external circuit, but no permanent chemical change in the electrolyte takes place. 2. AG = 0: Photoelectrosynthetic cell. The products of the homogeneous or heterogeneous photoredox process and the corresponding counterelectrode reactions are sufficiently stable to be collected for later use. Practically interesting is the endoergic photoelectrosynthesis (AG > 0 ) , producing species with stored chemical energy (fuel). The most important example is the splitting of water to oxygen and hydrogen. The exoergic process (AG<0) is also called photocatalytic, since the light provides only the activation energy for the reaction, which is otherwise thermodynamically possible even in the dark. Although no chemical energy is stored, useful products can sometimes result; an example is the synthesis of NH3 from N2 and H 2 . 5.10.2 Electrochemical photoemission

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Close to critical transition between the two regimes of association, a small variation of the af nity for the particle triggers the collective detachment of the loops In other words, when free energy of loop formation is close to balance the energy of hydrophobic binding, the trans to cis isomerization is expected to abruptly make the bound particle almost free In our experiments, azo-modi ed polyacrylates containing more than 1 mol% azo were tightly bound to micelles or bovine serum albumin (BSA) in the dark, but the association vanished for chains with lower integration level The binding transition occurs accordingly at a loop length of the order of 100 200, that is, at Floop #5 6 kT This energy is comparable to the energy of hydrophobic association, which can be estimated by B1 kT per hydrocarbon group transferred in a micelle core.

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In contrast to semiconductors, metals are usually not active as photoelectrodes owing to the fast thermal recombination of photogenerated charge carriers in the metal. The only light-stimulated charge transfer process at the electrolyte/metal electrode interface is photoemission of electrons. It is, in principle, similar to the conventional photoelectric effect in vacuum, i.e. it takes place under illumination with photons of sufficiently short wavelengths to overcome the binding energy of electron in the metal. Photoelectrons, emitted from the metal electrode into the electrolyte solution, are rapidly solvated and subsequently captured by a reducible solution species. The electrochemical photoemission was studied mostly at mercury electrode, first by M. Heyrovsky. The dependence of the photoemission current on the radiation frequency differs from that of a conventional vacuum photoemission. Gurevich et al. deduced the relationship: Ic = A(hv-hv0-eE)5/2 (5.10.1)

Note that because of steric interaction between the backbone and the hydrophilic heads of surfactants, the azobenzene may be partially penetrating in the micelle and the length of the spacer plays an important role Provided that cis trans isomerization can modify the energy of hydrophobic association by an order of magnitude of a few kT, light can trigger the transition between the two binding regimes Another interesting prediction of this schematic analysis is that an increase of the density of azobenzene must decrease the sensitivity to light (because of the decreasing contribution of the energy of loops) Experimentally, the optimal degree of modi cation was below 3 mol%, and most typically 1 2 mol% In the future, the goal of lowering the density of azobenzene in polymers should presumably be approached by designing new azobenzene-modi ed chains that bind even more tightly than the present ones.

where / c is the photocurrent, A is a constant, hv is the energy of the light quantum, hv0 is the threshold energy for photoemission at zero charge potential, e is the electron charge, and E is the electrode potential.

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Likewise, longer loops would be required to balance the association, but a similar switch by a few kT of the binding energy would still be enough to trigger the detachment In the case of.

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