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Yager KG, Barrett CJ. 2001. All optical patterning of azo polymer lms. Curr Opin Solid State Mater Sci 5:487 494. Yi DK, Kim DY. 2003. Novel approach to the fabrication of macroporous polymers and their use as a template for crystalline titania nanorings. Nano Lett 3:207 211. Yu YL, Nakano M, Ikeda T. 2003. Direct bending of a polymer lm by light. Nature 425:145 145. Zhang LF, Eisenberg A. 1995. Multiple morphologies of crew cut aggregates of polystyrene b poly(acrylic acid) block copolymers. Science 268:1728 1731. Zhang LF, Shen HW, Eisenberg A. 1997. Phase separation behavior and crew cut micelle formation of polystyrene b poly(acrylic acid) copolymers in solutions. Macromolecules 30:1001 1011. Zollinger H. 1961. Azo and Diazo Chemistry: Aliphatic and Aromatic Compounds. New York: Interscience Publishers. Zollinger H. 1991. Color Chemistry: Synthesis, Properties, and Applications of Organic Dyes and Pigments. 2nd ed. Weinheim: VCH.

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characterized by an ion-exchange equilibrium constant (cf Eq (635)) These concepts were developed kinetically by M Dole and thermodynamically by B P Nikolsky The last-named author deduced a relationship that is analogous to Eq (6310) It is approximated by Eq (6311) for pH 1-10 and corresponds well to deviations from this equation in the alkaline region The potentials measured in the alkaline region are, of course, lower than those corresponding to Eq (6311) The difference between the measured potential and that calculated from Eq (6311) is termed the alkaline or 'sodium' error of the glass electrode, and depends on the type of glass and the cation in solution (see Fig 66) This dependence is understandable on the basis of the concepts given above.

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The cation of the glass can be replaced by hydrogen or by some other cation that is of the same size or smaller than the original cation The smaller the cation in the glass, the fewer the ionic sorts other than hydrogen ion that can replace it and the greater the concentration of these ions must be in solution for them to enter the surface to a significant degree The smallest alkaline error is thus exhibited by lithium glass electrodes For a given type of glass, the error is greatest in LiOH solutions, smaller in NaOH solutions, etc Glass for glass electrodes must have rather low resistance, small alkaline error (so that the electrodes can be used in as wide a pH range as possible) and low solubility (so that the pH in the solution layer around the electrode is not different from that of the analyte).

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The incorporation of azobenzene into small amphiphilic molecules to make photosensitive surfactants has been much studied (Eastoe and Vespertinas, 2005; Lee et al., 2004; Shang et al., 2003; Orihara et al., 2001; Kang et al., 2000; Einaga et al., 1999; Sakai et al., 1999; Shin and Abbott, 1999; Yang et al., 1995; Shinkai et al., 1982). The main interest of such surfactants is to cause property changes of aqueous solutions in response to illumination as a result of the trans cis photoisomerization of the chromophore. Not surprisingly, many light-induced property changes are related to a disruption of micelles self-associated by azobenzene surfactant molecules (Lee et al., 2004; Shang et al., 2003; Kang et al., 2000; Shin and Abbott, 1999; Yang et al., 1995). For example, using 4,4u-bis (trimethylammoniumhexyloxy) azobenzene bromide, Shin and Abbot observed a signi cant decrease in dynamic surface tension upon illumination of UV light. They attributed this to a decrease in the number of micelles in solution that increases the rate of mass transport of surfactant molecules to the interface. In another study, Lee et al., demonstrated that the solution viscosity and gelation behavior of mixtures of azobenzene trimethylammonium bromide and a hydrophobically modi ed polymer could be reversibly controlled with UV and visible light. A light-induced dissolution of micelles formed by trans-azobenzene surfactants with the hydrophobic side groups of the polymer, acting as cross-links of polymer chains, was believed to be at the origin of the phenomenon. Generally, azobenzenecontaining surfactants display a higher critical micelle concentration (cmc) with

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These requirements are contradictory to a certain degree For example, lithium glasses have a small alkaline error but are rather soluble Examples of glasses suitable for glass electrodes are, for example, Corning 015 with a composition of 72% SiO2, 6% CaO and 22% Na2O, and lithium glass with 72% SiO2, 6% CaO and 22% Li2O Glasses containing aluminium oxide or oxides of other trivalent metals exhibit high selectivity for the alkali metal ions, often well into the acid pH region A glass electrode with a glass composition of llmol% Na2O, 18 mol% A12O3 and 71 mol% SiO2, which is sensitive for sodium ions and.

Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.

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