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One of the most interesting photoresponsive properties of azo polymers is the photoinduced birefringence and dichroism (Xie et al., 1993). The photoinduced anisotropy is caused by the disparity of the repeated trans cis isomerization of azo chromophores under linear polarized light irradiation. The most ef cient excitation occurs in the polarization direction, which can force the chromophores to continually change their orientation and to be eventually stabilized at the direction perpendicular to the polarization (Natansohn and Rochon, 2002). The effect shows potential applications in areas such as reversible optical data storage, optical switching and sensors. The colloids composed of azo polymers can be a new type of the colloid-based material that exhibits the photoinduced birefringence and dichroism (Li et al., 2005a). Figure 5.20 shows the chemical structure of an azo polymer (PNANT) that has been prepared for the purpose. PNANT contains both pseudostilbenetype azo chromophores and ionizable carboxyl groups in the side chain in a random sequence. PNANT was synthesized from a PAC sample with the average degree of polymerization (DP) of 239 and a polydispersity index of 1.53. The precursor polymer containing anilino moieties was synthesized by the reaction between a proper amount of N-ethyl-N-(2-hydroxyethyl)aniline and PAC through the Schotten Baumann reaction. Unreacted acyl chloride groups were then hydrolyzed to obtain the COOH groups after the reaction. Finally, PNANT was obtained by azo coupling reaction between the precursor polymer and diazonium salt of 4-nitroaniline. In this reaction, the molar ratio of the diazonium salt to the anilino moieties of the precursor polymer was 1.1 in order that the anilino moieties were completely reacted. The details of these reactions can be seen in Li et al. (2005a), Wu et al. (2001), and Wang et al. (1997b). The average DF,

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2

(6.2.21)

Figure 7.8. Schematic representation of the formation of a physical gel by transient associations with nanoparticles in semidilute solutions of polymer and the corresponding rheological signature. The elastic (Gu) and loss (Guu) moduli are plotted as a function of the frequency of the oscillating strain for samples containing the same polymer concentration (1 wt%) and bovine serum albumin at 0, 0.03, and 0.2 g/L, respectively.

The sign of the cross coefficient Lw<t> determines the direction of the electroosmotic flux and of the cation flux. From Eq. (6.2.12) we have

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the concentration of physical cross-links, X, varies in proportion to (i) the density of interchain contacts, (ii) the probability of having on protein-free segment facing a protein-bound segment, and (iii) a binding constant that re ects the free energy of association of at least two segments of the chain on one protein. In a simpli ed version of the theory, it is X$k2 f 1 f C3u=3u

* ^'

7:2

(6.2.22)

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Figure 7.9. Effect of light on the connectivity of physical gels. The relaxation modulus in stress relaxation experiment is plotted after application at time zero of a xed strain, for the same sample that was either incubated for 24 h in the dark (dark-adapted) or exposed to UV in the rheometer. For details on the samples, see Pouliquen and Tribet (2006).

423 where, for a cation-exchanger membrane, > 0 and, for an anionexchanger membrane, < 0 . Thus, the electroosmotic flux for an anionexchanger membrane will go in the opposite direction. When a change in pressure Ap (the electroosmotic pressure) stops the electroosmotic flux (/ v = 0> AJT = 0), then the first of Eqs (6.2.18) gives (6.2.23) Figure 6.4 depicts the formation of the electroosmotic pressure. The last experiment involves measurement of the membrane potential (in the last of Eqs (6.2.18), j = 0 and Ap = 0), for which it follows from Eq. (6.2.16) that

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