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Photoresponsive behavior of the hybrid colloids depends on the composition and distribution of the components in the colloids (Deng et al., 2007). The hybrid colloid composed of BP-AZ-CA and PEAPE, whose preparation has been discussed in Section 5.3.4, is further discussed herein concerning its photoresponsive properties. As PEAPE and BP-AZ-CA contain HEAZ moieties and ACAZ moieties, the colloids can show photoinduced variation related to the azobenzenetype and pseudostilbene-type chromophores. Figure 5.16 shows the UV-vis spectra of the stable suspensions of the PEAPE/ BP-AZ-CA (1:1, wt:wt) hybrid colloids before and after UV light (365 nm) irradiation. For single-component colloids of PEAPE and BP-AZ-CA, the p p* transition bands (lmax) appear at 365 and 470 nm. For the hybrid colloids, the absorption bands at 365 and 455 nm can be assigned to the HEAZ and ACAZ moieties of the polymers. The new band appearing at 387 nm could be the absorption band because of the HEAZ/ACAZ charge-transfer complex. Upon the light irradiation, the absorption at 365 and 387 nm decreases gradually as the result of the trans-to-cis isomerization of the HEAZ chromophores. No variation is observed for absorption band at 455 nm because trans cis isomerization of the ACAZ moieties (a pseudostilbene-type chromophore) is too fast to be detected at the timescale given here (Rau, 1990). The relative absorbance can be given as At/ Aorigin, where Aorigin and At are the absorbance at 365 nm before the light irradiation and after the irradiation for different time periods. At/Aorigin can be used to indicate the relative amount of the trans isomers remaining at t time, and its variation represents the kinetics of the photoisomerization. The variations can

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The electrical potential in the layer of the liquid moving only negligibly at the surface of the pores is equal to the electrokinetic potential (see page 242). At the middle of the pore, the electric potential and its

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It was developed by a group of engineers from Compaq, IBM, HP, Intel, Microsoft, and Sun iLO Integrated Lights-Out remote management from HP InfiniBand A scalable, high-speed, switched fabric network, often used in HPCC due to its speed and IPC functionality InfiniBand (IB) switch modules are available for a number of blade systems Servers connect to an IB network through a host channel adapter (HCA) IP Internet Protocol is a data-oriented networking protocol used as part of the Internet Suite for moving data across a packet-switched network It sits in the network layer (layer 3) of the OSI model IPC Inter-Process Communications is the method used to send information between two threads in one or more processes, whether they are running on the same or different processors.

1.00 Absorbance (a.u.)

gradient d(f>/dy equal zero and also dv/dy =0. Integration of Eq. (6.2.9) yields the Helmholtz-Smoluchowski equation dcbet v=^r~ (6.2.10)

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0.25 300 400 500 Wavelength (nm) 600

For a simple model of the membrane it is assumed that N cylindrical pores with radius r are located perpendicular to a membrane of thickness d. The resistance of such a membrane is given by the relationship d d<bd ^

Figure 5.16. Variation of the UV-vis spectra of the colloidal dispersions induced by the UV light irradiation. The dispersions were obtained by adding water into a THF solution of PEAPE/BP-AZ-CA (1:1, wt:wt). Source: From Deng et al., 2007.

(6.2.11)

IPv6 Internet Protocol version 6 is the latest version of the IP standard used by network devices iSER iSCSI Extensions for RDMA is an IETF extension to iSCSI that adds support for a direct-access remote DMA-based transport (such as InfiniBand) under iSCSI, offering better performance than iSCSI over TCP or using a TCP Offload Engine (TOE) iSCSI iSCSI is a protocol for encapsulating (and encrypting, if necessary) SCSI (Small Computer Systems Interface) commands into IP packets to transfer blocks of data from storage devices connected to an IP network to servers connected to the IP network The iSCSI protocol is used to create an IP storage area network (SAN) versus a Fibre Channel SAN ISL Interswitch Link is the link between two Fibre Channel switches using E-ports on each switch ISL trunking Interswitch Link trunking is the grouping of multiple ISLs into a single logical path or trunk.

where K is the conductivity of the pores of the membrane and j is the current density (referred to the unit surface area of the membrane). The volume flux of the liquid through the membrane (electroosmotic flux) then is eti Jv = vjir2N =

be best tted by the rst-order exponential decay function At =Aorigin A0 A1 exp t=T1 5:2

(6.2.12)

ISL trunking provides framelevel load balancing over the individual ISLs and improves performance by reducing congestion IT Information Technology is the group within a company that is responsible for managing and processing information They support the computers and their associated peripherals, as well as computer processes (used to be called Management Information Systems, or MIS) KVM Keyboard, video, and mouse generally refers to the interface over which the keyboard, video, and mouse communicate to a server A KVM switch, which is typically included in a blade chassis, allows a remote user to connect to any blade server within the chassis KVM over IP allows a remote user to connect over an IP network kW Kilowatt is a unit that measures power It is equal to 1000 watts Blade systems require roughly an average of 30kW per rack, and growing.

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