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This polydispersity may cause a more gradual association (for instance, only the segments with highest hydrophobicity would contribute to the association at low micelle concentration) This drawback should be limited by using longer chains (decrease of the polydispersity between chains) and presumably by using chromophores that make a signi cant change of the energy of binding upon irradiation, of the order of several kT Second, the degree of photoisomerisation is usually not complete under UV exposure (usually B80% of cis isomer and 20% residual trans isomers) (Morishima et al, 1992) If the association strength is high enough, the 20% residual trans azobenzene still present under UV exposure would cause the formation of loops that are just ve times longer than the one formed in the dark, and consequently no detachment of the nanoparticles occurs.

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The power flux corrected for atmospheric absorptions equals about 1 kW/m2 if the Sun stands at zenith and the sky is clear. This situation is customarily labelled AM 1 (one standard air mass). The total world consumption of energy (ca. 3.1020 J/year) can be met by converting the solar energy impinging on about 0.01 per cent of the Earth's surface, which is about 0.3 per cent of the desert areas. The research on solar energy conversion is further encouraged by the existence of natural photosynthesis, which provides all the fossile energy resources of the Earth. The natural photosynthesis transforms about 0.1 per cent of the solar energy impinging on the Earth, but the energy conversion in green plants is not as efficient as that attained by currently available photovoltaic cells and other artificial devices. The solar energy conversion efficiency is defined as: CE = Pout/Ps (5.10.34) where Fout is the maximum power output of the cell per unit illuminated area. For a regenerative photoelectrochemical cell, the maximum value of Pout has to be derived from the photocurrent/potential characteristic of the cell (Fig. 5.64). The quality of the cell is also described by the so-called fill factor,/:

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This document provides a high-level overview of the CDDLM space by describing requirements, analyzing use cases, and providing an overview of the related work within OGF, other standard bodies, and in industry and academia in general. The document sets the stage for the follow-up documents that will present in more detail the language, component model, and basic CDDLM services.

Assuming that the regime of strong binding is reached in the dark (Fbinding (trans)WkT Ln N, with N the length between successive azo in the chain), the additional criterion for detachment in presence of residual trans groups writes Fbinding (trans)okT Ln (5 N) Therefore, the effective window for controlling the binding is limited to a range of free energy of 16 kT In the working examples shown earlier, this energy was probably adjusted by proper choice of the chemistry of the azobenzene side groups (for instance, spacer length and hydrophobicity) Among the dif culty added by this constraint, it is indeed expected that the response becomes more sensitive to subtle local interactions, for example, with the micelle hydrophilic head groups..

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To install and operate complex systems such as n-tier systems more efficiently and automatically, it is necessary to specify and manage, as a unit, a diverse set of application-related information. The Application Contents Service (ACS) provides central management of such application information. The ACS specification will focus on two main topics: Application Repository Interface (ARI), specifying repository service and its interface to Application Contents; and Application Archive Format (AAF), specifying archive format to register a set

In the semidilute regime for the particle polymer complexes, the binding may connect several chains together. Viscosity enhancement and elasticity are the macroscopic signatures of the connectivity. The sol gel transition occurs abruptly at an average density of about one transient cross-link per chain. In the vicinity of this (critical) transition, both viscosity and the elastic modulus of the solution display a dramatic sensitivity to small variation of the cross-link concentration. The sol gel transition provides accordingly an additional ampli cation of the photovariation of binding. Signi cant magnitude of the photoswitch of viscosity was recently achieved using conventional hydrophobically modi ed polymers

\p.L\J.oJ)

where is the maximum photocurrent density (at short circuit) and AZs hax is the maximum photovoltage (at open circuit).

in combination with photochromic micelles (Lee et al, 2004) Micelles with ca 50 100 azo-surfactants play the role of a photoresponsive cross-link, and their concentration vanishes upon exposure to UV The system requires, however, that the concentration of nanoparticles (here azo-containing micelles) is made extremely unstable under UV light, which constraints the surfactant concentration to be maintained close to the critical micellar concentration The principal ampli cation of the response is because of self-assembly of the surfactant In addition, the boundary condition of about one cross-link per chain corresponds to the binding of 50 100 azo-surfactants per chain, in equilibrium with possibly a similar amount of unbound ones To decrease the amount of azobenzene signi cantly, we proposed recently, the use of azo-modi ed polymers connected by nonresponsive nanoparticles.

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